Water Vapor Adsorption on Chemically Treated Activated Carbon Cloths

نویسندگان

  • E. Dimotakis
  • M. Gal
چکیده

Water vapor adsorption on activated carbon cloth (ACCBO) which has been oxidized to a level of 32% oxygen exhibits a unique isotherm with uniform hysteresis of small magnitude upon desorption. In contrast the adsorption on untreated ACCBO and chemically modified ACCBO (7.8% Cl), ACCBO (16% Cl), and ACCBO (4% N), exhibits sigmoidal isotherms with hysteresis loops of varying magnitudes. The latter ACCs display high capacity for moisture removal at relative humidities >50%. At saturation, all treated cloths exhibit high adsorption capacities for water (0.5-0.67 m u g of fiber) and 100% desorption upon heating to 100 "C. The untreated and treated ACCBO samples exhibited no degradation upon heating to 100 "C. Total water adsorption volumes are lower than the total nitrogen pore volumes for all samples except for the ACC2O (32% 01, which adsorbs similar volumes of both adsorbates.

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تاریخ انتشار 2001